Improved mistake

"We were studying making hydrogen in microbial electrolysis cells and we kept getting all this methane," said Bruce E. Logan, Kappe Professor of Environmental Engineering, Penn State. "We may now understand why."
Methanogenic microorganisms do produce methane in marshes and dumps, but scientists thought that the organisms turned hydrogen or organic materials, such as acetate, into methane. However, the researchers found, while trying to produce hydrogen in microbial electrolysis cells, that their cells produced much more methane than expected.
"All the methane generation going on in nature that we have assumed is going through hydrogen may not be," said Logan. "We actually find very little hydrogen in the gas phase in nature. Perhaps where we assumed hydrogen is being made, it is not."  

The cells are about 80 percent efficient in converting electricity to methane and because they use carbon dioxide as feed stock, would be carbon neutral if the electricity comes from a non-carbon source such as solar or wind power.